赣南崇义淘锡坑钨矿床氢、氧、硫同位素地球化学研究   总被引：11，自引：2，他引：9  

宋生琼  胡瑞忠  毕献武  魏文凤  石少华 《矿床地质》2011,30(1):1-10

赣南崇义县淘锡坑钨矿位于南岭东西向构造带东段与武夷山NE-NNE向构造带南段的复合部位,属于以石英脉型黑钨矿为主的钨多金属矿床.文章通过氧、氧、硫同位素地球化学特征的研究,探讨了淘锡坑钨矿成矿流体的来源及演化.研究结果显示:δD值介于-77‰～-45‰之间;石英矿物的δ18O值介于+7.3‰～+12.2‰之间,计算给出...  相似文献   

王水溶样-电感耦合等离子体发射光谱法同时测定铁铜铅锌硫化物矿石中8个元素   总被引：5，自引：5，他引：0  

温宏利  马生凤  马新荣  王蕾  范凡  巩爱华 《岩矿测试》2011,30(5):566-571

建立了王水溶样-电感耦合等离子体发射光谱法同时测定铁、铜、铅、锌硫化物矿中Cu、Pb、Zn、As、Ag、Cd、Hg和Mo等8个元素的分析方法。确定了方法的溶矿及测定条件,用国家一级标准物质GBW07162(多金属贫矿石)和GBW07164(多金属矿石)进行精密度实验,除个别元素外,大多数的元素精密度(RSD,n=11)小于5%,准确度(RE)小于10%。通过一系列硫化物矿石标准物质进行方法验证,检测结果基本都在标准值的误差范围内,符合地质矿产开发的要求。方法简单,同时测定元素较多,线性范围宽,检出限低,尤其有利于硫化物矿石中的亲硫元素As、Ag、Hg的分析,实用性强。  相似文献   

硫化物及硫酸盐中硫同位素制样装置及其反应器研制     

李振涛  刘汉彬  金贵善  李军杰  钟芳文 《国外铀金地质》2011,(1):52-54

研制了一种新型硫化物及硫酸盐中硫同位素制样装置及其反应器。实验证明,采用该装置及其反应器制样具有真空度好、使用方便、无污染、制样效率高和成本低等优点。所生成的二氧化硫具有纯度高,分析结果准确、可靠等特点,完全能满足硫化物和硫酸盐中硫同位素分析测试的制样要求。  相似文献   

不同地质背景地热系统水-岩作用下温泉水的地球化学特征——以重庆市温塘峡背斜温泉、滇东小江断裂带温泉为例   总被引：1，自引：1，他引：0  

杨雷  肖琼  沈立成  伍坤宇 《中国岩溶》2011,30(2):209-215

本文以重庆市温塘峡背斜和滇东小江断裂带出露温泉为例,探讨了其水文地球化学特征的差异。研究发现,由于地质背景条件基本相同,温塘峡背斜出露的温泉水文地球化学特征比较接近,水化学类型为SO4-Ca（Mg）型,而小江断裂带温泉水文地球化学特征差异较大,泉水水化学类型主要有HCO3-Na型（YN1）、HCO3-Ca型（YN2）、SO4-Ca（Mg）型（YN3和YN5）和SO4-HCO3-Ca-Na型（YN4）,这与各泉点所处地质背景条件不同有很大关系。此外,通过对Na-K-Mg和Na-K-Mg-Ca图解模型的解读得出,所有样品均未达到水-岩平衡,仅有YN1泉点样品接近完全平衡线,表明YN1接近水-岩作用平衡状态,并由上述图解模型估算得到YN1点热储温度大概为100~120℃,与运用SiO2温标计算的热储温度（133~139℃）相差不大。此外,水化学特征和Na-K-Mg-Ca图解分析也表明,YN2与温塘峡背斜温泉水-岩作用过程比较相似。  相似文献   

内蒙古龙头山多金属硫化物矿床同生重晶石流体包裹体特征——海相热水沉积成因证据     

孙兴国  李永兵 《岩石矿物学杂志》2011,30(4):637-644

龙头山多金属硫化物矿床位于内蒙古大兴安岭中南段东坡,海西期地槽褶皱带西拉木伦河深大断裂北侧.野外地质研究发现,该矿床主要发育层状和筒柱状两类矿化,两类矿化的产状、蚀变、矿物特征等显示出典型的海底热水沉积成矿作用特征.对与该矿床金属硫化物同生沉积的重晶石进行流体包裹体岩相学研究发现,重晶石中的包裹体反映了热水沉积成矿期快...  相似文献   

嗜酸性氧化亚铁硫杆菌与硫化物矿石相互作用的实验研究   总被引：2，自引：0，他引：2  

欧阳冰洁  陆现彩  陆建军  李娟  王朝华  朱婷婷  王汝成  耿建华 《岩石矿物学杂志》2011,30(6):1021-1030

实验研究了嗜酸性氧化亚铁硫杆菌(Acidithiobacillus ferrooxidans,简称A.f)与硫化物矿石之间的相互作用,以观察不同矿石矿物发生微生物氧化和形成次生矿物的差异。采用ICP-OES分析了反应前后溶液成分变化,利用扫描电子显微镜(SEM)、能谱分析(EDS)和X射线衍射(XRD)等分析手段研究了矿石表面形貌的变化和沉淀物的矿物组成。分析结果表明,A.f对同一矿石中不同矿物作用强度存在明显差异,方铅矿、闪锌矿发生强烈氧化分解,而与黄铁矿的相互作用则较弱。这种差异可能与矿物晶体结构有关,在多种矿物并存的情况下,可能发生了原电池反应,作为阴极的黄铁矿受到保护,而作为阳极的闪锌矿、方铅矿的氧化作用得到促进,总体上表现为A.f对矿石硫化矿物的选择性作用。  相似文献   

The Impact of Aqueous Medium on Gas Yields and Kinetic Behaviors of Hydrogen Isotope Fractionation during Organic Matter Thermal Degradation     

LU Shuangfang  WANG Min  XUE Haitao  LI Jijun  CHEN Fangwen  XU Qingxia 《《地质学报》英文版》2011,85(6):1466-1477

In order to recognize the impact of aqueous medium on gas yields and the kinetic behaviors of hydrogen isotope fractionation during organic matter thermal degradation, the gold tube apparatus was used to conduct thermal simulation experiments by mixing the nC18 with the water of different properties and proportions. The yields of natural gas components, the relation among hydrogen isotope composition of each component and the experimental temperatures vs. heating rates have been obtained, and the results indicate that under the higher temperature conditions, the hydrous experiment has obvious impact on gas yields, such as when more water is added, higher amounts of hydrocarbon gas and H2 are yielded, and the existence of water obviously prolongs the temperature interval with the existence of heavy hydrocarbon gas. It also shows that the hydrogen isotope of hydrocarbon gas generated by the hydrous experiment is obviously lighter than that generated by the anhydrous experiment, and with the increasing amount of added water, the δD value of hydrocarbon gas gradually decreases. Compared with gas yields, the variation of δD value is more sensitive to aqueous medium in the thermal simulation experiment. However, compared with the amount of the added water, the aqueous medium property has smaller impact on the gas yields, which still shows the inherit effect on hydrogen isotope composition of aqueous medium. Through the model simulation and the isotope fractionation behavior analysis, it is validated that the hydrogen isotope fractionation process can be well described by the chemical kinetic model. The difference of reaction fraction of normal methane and D-containing methane is large, corresponding to the same activation energy. The content of normal methane is obviously higher in the part with lower activation energy, while the content of D-containing methane is higher in the part with higher activation energy. Therefore, it will result in larger hydrogen isotope fractionation amplitude, and the δD values will be more sensitive to the variation of maturity. Meanwhile, the average activation energy of methane generation from nC18 in the hydrous experiment is higher than that in the anhydrous experiment, and the greater amount of added water, the larger the average activation energy of methane generation reaction. This has laid foundation for its exploratory application in the study of gas reservoir forming history and the gas-source correlation, which indicates the research and application prospects in this orientation.  相似文献   

Water Role and Its Influence on Hydrogen Isotopic Composition of Natural Gas during Gas Generation     

LI Jijun  LU Shuangfang  WU Wei  XUE Haitao  XU Qingxi  GENG Jie  YU Yinghua 《《地质学报》英文版》2011,85(5):1203-1210

In order to discuss the role and influence of water during the generation of natural gas, the participation mechanism of water during the evolution of organic matter and its influences were summarized. In addition, we carried out an anhydrous cracking experiment of oil extracted from the Feixianguan Formation source rock in a closed system, which led to the establishment of the kinetic models for describing carbon and hydrogen isotopic fractionation during gas generation from organic matter. The models were calibrated and then applied to the northeastern Sichuan Basin. By combining a series of gas generation experiments from octadecane pyrolysis without water or with distilled water in varying mass proportions, several results were proved: (1) the hydrogen isotopic composition of natural gas becomes lighter with the participation of formation water; (2) we can quantitatively study the hydrogen isotopic fractionation with the kinetic model for describing carbon isotopic fractionation; (3) more abundant and reliable geological information can be obtained through the combined application of carbon and hydrogen isotopic indices.  相似文献   

遵义市2009/2010年秋冬春连旱事实及形成原因初析     

姚正兰  王君军 《地球科学进展》2011,26(10):1109-1115

2009年秋季到2010年初春,遵义市出现了特大干旱,对农业、林业、人畜饮水、水利电力等方面造成严重的危害和巨大的损失。详细分析干旱期间的气象要素,从秋季9月到初春3月的总降水量不足常年同期平均值的一半,并与历史上的秋冬干旱年份进行了比较,发现本次干旱期间遵义市大部分地方降水量等多项气象要素突破历史最少记录,因此认为2...  相似文献   

缅甸联邦MTT金铜矿床成矿地质特征          下载免费PDF全文

徐强 《江苏地质》2011,35(4):375-378

缅甸联邦实皆省MTT金铜矿床位于曼德勒以西约200km新生代安山岩中,属块状硫化物金铜矿床。对其成矿地质特征进行了研究,有助于在新生代安山岩中发现相同类型的矿床。矿体产在缅甸中部盆地地体之西缘,赋矿地层(即含矿岩系)为陆相安山岩,硫化物矿体呈层状、似层状和透镜体状。矿石具块状构造,矿石中主要成矿元素为Cu、Au、S;铜矿石品位较高,属富铜矿。该类型矿床的找矿标志是:具有低阻高极化的物探异常。  相似文献